Homogeneous hydrogenation of C=N bonds remains a challenge to catalysis, particularly when enantioface selectivity is needed. During the past decade some progress has been made in this area; however, high enantioselectivities has been obtained only for limited classes of imines or their derivatives. There is thus a great need to develop new catalyst systems for asymmetric hydrogenation of C=N bonds. This book begins with a brief literature survey on the mechanisms of C=N hydrogenation, followed by a detailed description of ionic hydrogenation, an alternative method and new concept for hydrogenation. The main focus of the book is on the scope and mechanism of ruthenium-catalyzed ionic hydrogenation reactions. This information should be useful to industrial scientists who are seeking chemoselective and stereoselective hydrogenation processes, as well as to academic researchers who are interested in reaction mechanisms and catalyst design.
Homogeneous hydrogenation of C=N bonds remains a challenge to catalysis, particularly when enantioface selectivity is needed. During the past decade some progress has been made in this area; however, high enantioselectivities has been obtained only for limited classes of imines or their derivatives. There is thus a great need to develop new catalyst systems for asymmetric hydrogenation of C=N bonds. This book begins with a brief literature survey on the mechanisms of C=N hydrogenation, followed by a detailed description of ionic hydrogenation, an alternative method and new concept for hydrogenation. The main focus of the book is on the scope and mechanism of ruthenium-catalyzed ionic hydrogenation reactions. This information should be useful to industrial scientists who are seeking chemoselective and stereoselective hydrogenation processes, as well as to academic researchers who are interested in reaction mechanisms and catalyst design.
An Overview of Renewable Energy Global energy demand is an ever-increasing crisis due to massive industrialization, automation and the socio-economic lifestyle of the...
Ionic and Organometallic-Catalyzed Organosilane Reductions provides an up-to-date, comprehensive review of reductions with organosilanes. Both ionic and catalyst-mediated reaction types are included,...
During the oil embargo, in the winter 1973174, parts of Western Europe present ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high ways, no crowds at ski resorts and other...
For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel...
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