Foreword. 1. Historical Perspective of Organometallic Thermochemistry; H.A. Skinner. 2. Combustion Calorimetry of Organometallic Compounds; G. Pilcher. 3. Organo-f-Element Thermochemistry, Implications for Reactivity and Bonding from Metal-Ligand Bonding Energetics; M.A. Giardello, W.A. King, S.P. Nolan, M. Porchia, C. Sishta, T.J. Marks. 4. The Role of Bond Energies in Hydrocarbon Activation by Transition Metal Centers; W.D. Jones, R.M. Chin, L. Dong, S.B. Duckett, E.T. Hessell. 5. Rh-C Bond Dissociation Enthalpies for Organometallic Derivatives of Rhodium Porphyrins; B.B. Wayland. 6. Solution Thermochemistry of Organometallic Compounds Using Photoacoustic Calorimetry: Enthalpies of Ligand Exchange, Metal-Ligand Bonds, and Metal-Solvent Interactions; T.J. Burkey. 7. Electrochemistry of some Organic and Organometallic Radicals and their Application in Thermochemical Cycles; D.D.M. Wayner. 8. Derivative Cyclic Voltammetry: Applications in the Investigation of the Energetics of Organometallic Electrode Reactions; M. Tilset. 9. The Use of Calorimetric and Sublimation Techniques to Study Bond Properties in Organometallic Compounds; A.S. Carson. 10. Estimating Enthalpies of Sublimation of Hydrocarbons; J.S. Chickos, D.G. Hesse, J.F. Liebman. 11. Derivation of Thermodynamic Quantities from Kinetic Measurements in Gas Phase Silane Chemistry; R. Walsh. 12. Bond Enthalpy Transferability -- Is It Achievable? J.A. Connor. 13. Estimates of Thermochemical Data for Organometallic Compounds; J.A. Martinho Simões. 14. Bonding and Solvation Energetics for Organometallic Gas-PhaseMolecules and Ions: Experimental Approaches and Thermodynamic Insights; D.E. Richardson. 15. Gas-Phase Acidities of Transition-Metal Carbonyl and Trifluorophosphine Hydrides; A.E. Stevens Miller, T.M. Miller. 16. Bond Strengths in Transition Metal Carbonyl Anions; L.S. Sunderlin, R.R. Squires. 17. Fundamental Gas Phase Studies of the Mechanism and Thermochemistry of Organometallic Reactions; J.L. Beauchamp, P.A.M. van Koppen. 18. Guided Ion Beam Studies of the Energetics of Organometallic Species; P.B. Armentrout, D.E. Clemmer. 19. A Guide to Density Functional Theory and its Practical Applications to the Energetics of Organometallic Species; T. Ziegler. 20. Theoretical Models for Organometallic Reactions; M.R.A. Blomberg, P.E.M. Siegbahn, M. Svensson, J. Wennerberg. List of Posters and Contributed Oral Presentations. Subject Index.
Foreword. 1. Historical Perspective of Organometallic Thermochemistry; H.A. Skinner. 2. Combustion Calorimetry of Organometallic Compounds; G. Pilcher. 3. Organo-f-Element Thermochemistry, Implications for Reactivity and Bonding from Metal-Ligand Bonding Energetics; M.A. Giardello, W.A. King, S.P. Nolan, M. Porchia, C. Sishta, T.J. Marks. 4. The Role of Bond Energies in Hydrocarbon Activation by Transition Metal Centers; W.D. Jones, R.M. Chin, L. Dong, S.B. Duckett, E.T. Hessell. 5. Rh-C Bond Dissociation Enthalpies for Organometallic Derivatives of Rhodium Porphyrins; B.B. Wayland. 6. Solution Thermochemistry of Organometallic Compounds Using Photoacoustic Calorimetry: Enthalpies of Ligand Exchange, Metal-Ligand Bonds, and Metal-Solvent Interactions; T.J. Burkey. 7. Electrochemistry of some Organic and Organometallic Radicals and their Application in Thermochemical Cycles; D.D.M. Wayner. 8. Derivative Cyclic Voltammetry: Applications in the Investigation of the Energetics of Organometallic Electrode Reactions; M. Tilset. 9. The Use of Calorimetric and Sublimation Techniques to Study Bond Properties in Organometallic Compounds; A.S. Carson. 10. Estimating Enthalpies of Sublimation of Hydrocarbons; J.S. Chickos, D.G. Hesse, J.F. Liebman. 11. Derivation of Thermodynamic Quantities from Kinetic Measurements in Gas Phase Silane Chemistry; R. Walsh. 12. Bond Enthalpy Transferability -- Is It Achievable? J.A. Connor. 13. Estimates of Thermochemical Data for Organometallic Compounds; J.A. Martinho Simões. 14. Bonding and Solvation Energetics for Organometallic Gas-PhaseMolecules and Ions: Experimental Approaches and Thermodynamic Insights; D.E. Richardson. 15. Gas-Phase Acidities of Transition-Metal Carbonyl and Trifluorophosphine Hydrides; A.E. Stevens Miller, T.M. Miller. 16. Bond Strengths in Transition Metal Carbonyl Anions; L.S. Sunderlin, R.R. Squires. 17. Fundamental Gas Phase Studies of the Mechanism and Thermochemistry of Organometallic Reactions; J.L. Beauchamp, P.A.M. van Koppen. 18. Guided Ion Beam Studies of the Energetics of Organometallic Species; P.B. Armentrout, D.E. Clemmer. 19. A Guide to Density Functional Theory and its Practical Applications to the Energetics of Organometallic Species; T. Ziegler. 20. Theoretical Models for Organometallic Reactions; M.R.A. Blomberg, P.E.M. Siegbahn, M. Svensson, J. Wennerberg. List of Posters and Contributed Oral Presentations. Subject Index.
When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26...
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