Fuel cells which were first employed in spacecraft, are part of the ongoing pursuit for renewable energy sources, and environmentally compatible electric power generation. Recent enhancements in design and materials might establish fuel cells in a sustainable hydrogen energy economy (SHEE) as viable alternatives to the internal combustion engine. This study investigates the conductive properties of metal-oxide thin films by developing a new deposition technique called dual channel ultrasonic spray pyrolysis (DC-USP). The DC-USP process has proved to be a reliable and cost-effective method to fabricate thin films. We have then created a novel mixed ionic electronic conductor (MIEC) composed of two metal-oxides: lanthanum strontium ferrite and copper-doped bismuth vanadate (LSF.40:BiCuVOx.10). This composite material can contribute to solve the major outstanding problem of the three-phase boundary (TPB) that limits the oxygen reduction reaction to within a microscopic region near the cathode-electrolyte interface in the SOFC device. Results show that at a temperature of 550 C, the average bulk resistivity for LSF.40:BiCuVOx.10 films was 2.08 ohm-cm (a conductivity of 0.48 S/cm).
A Study of the Conductive Properties of Nanostructured Metal Oxide Films
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Fuel cells which were first employed in spacecraft, are part of the ongoing pursuit for renewable energy sources, and environmentally compatible electric power generation. Recent enhancements in design and materials might establish fuel cells in a sustainable hydrogen energy economy (SHEE) as viable alternatives to the internal combustion engine. This study investigates the conductive properties of metal-oxide thin films by developing a new deposition technique called dual channel ultrasonic spray pyrolysis (DC-USP). The DC-USP process has proved to be a reliable and cost-effective method to fabricate thin films. We have then created a novel mixed ionic electronic conductor (MIEC) composed of two metal-oxides: lanthanum strontium ferrite and copper-doped bismuth vanadate (LSF.40:BiCuVOx.10). This composite material can contribute to solve the major outstanding problem of the three-phase boundary (TPB) that limits the oxygen reduction reaction to within a microscopic region near the cathode-electrolyte interface in the SOFC device. Results show that at a temperature of 550 C, the average bulk resistivity for LSF.40:BiCuVOx.10 films was 2.08 ohm-cm (a conductivity of 0.48 S/cm).
Metal oxides and particularly their nanostructures have emerged as animportant class of materials with a rich spectrum of properties and greatpotential for device applications. In this book, ...
This book primarily covers the fundamental science, synthesis, characterization, optoelectronic properties, and applications of metal oxide nanomaterials. It discusses the basic aspects of synthetic...
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